Author: Zhong, Jia-Jing; Zhan, Shun-Ze; Li, Yanzhou; Guo, You-Shi; Ng, Seik Weng; Deng, Yi-Fei; Li, Dan

Source: Inorganic CHemistry, 2022, 61, 10624-10628.

DOI: 10.1021/acs.inorgchem.2c01478

Abstract:

Polymeric {Cu₆[(m₃-(h²:h²:h²)₂-C₆₀](FPz)₆Cl·3C₆H₅Cl}¥ [FPz = 4-(trifluoromethyl)pyrazolate], synthesized solvothermally with chlorobenzene as the solvent, is a doubly-connecting trans bis-adduct hexanuclear cuprofullerene that has copper in mixed valence. The compound is an example of a metallofullerene having semiconductivity character.